Homogeneous Precious Metal Catalysts for the Pharmaceutical, Agrochemical & Finechemical Industry
Complex molecules like active ingredients in pharmaceutical or agrochemical preparations are often only obtainable through catalysis. Moreover, large scale chemical products like building blocks for polymers or additives for plastics are also produced more efficiently by using catalysts.
Platinum group metals (PGM) – platinum, palladium, rhodium, osmium, iridium and ruthenium – are often preferred as catalytic metal due to their outstanding catalytic activity and selectivity. Especially the homogeneous PGM catalysts (salts or metalorganic compounds) that are completely soluble in the reaction mixture enable high yields at relatively mild conditions (lower temperature and pressure).
Find your solution in the comprehensive portfolio of homogeneous catalysts for chemical and pharmaceutical processes.
47 Results
Best Delivery | Quotation | ||||||||
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5027767 | Palladium Acetate | 3375-31-3 | Pd | 47.50 - 48.50 | Solid | Pd3(CH3COO)6 | EMEA, APAC | Online available | |
5027784 | Rhodium Chloride | 13569-65-8 | Rh | 37.00 - 42.00 | Solid | RhCl3 | EMEA, APAC | Online available | |
5027796 | Osmium Tetroxide | 20816-12-0 | Os | 75.00 | Solid | OsO4 | EMEA, APAC, AMER | Online available | |
5027797 | Osmium Tetroxide 0.1g | 20816-12-0 | Os | 75.00 | Solid | OsO4 | EMEA, APAC, AMER | Online available | |
5027798 | Osmium Tetroxide 0.25g | 20816-12-0 | Os | 75.00 | Solid | OsO4 | EMEA, APAC, AMER | Online available | |
5027799 | Osmium Tetroxide 0.5g | 20816-12-0 | Os | 75.00 | Solid | OsO4 | EMEA, APAC, AMER | Online available | |
5027800 | Osmium Tetroxide 1g | 20816-12-0 | Os | 75.00 | Solid | OsO4 | EMEA, APAC, AMER | Online available | |
5027813 | Potassium Osmate | 10022-66-9 | Os | 51.50 - 52.50 | Solid | K2OsO2(OH)4 | EMEA, APAC, AMER | Request a quote | |
5027815 | Potassium Osmate | 10022-66-9 | Os | 51.50 - 52.50 | Solid | K2OsO2(OH)4 | EMEA, APAC, AMER | Online available | |
5027818 | Osmium Chloride | 14996-60-2 | Os | 53.00 - 57.00 | Solid | OsCl3 | EMEA, APAC, AMER | Online available | |
5027823 | Potassium Hexachloroosmate | 16871-60-6 | Os | 38.60 - 39.40 | Solid | K2OsCl6 | EMEA, APAC, AMER | Request a quote | |
5050596 | Osmium | 7440-04-2 | Os | 40.00 | Solid | Os | EMEA, APAC, AMER | Request a quote | |
5081598 | Potassium Osmate | 10022-66-9 | Os | 45.00 | Solid | K2OsO2(OH)4 | EMEA, APAC, AMER | Request a quote | |
5100251 | Bis(dibenzylideneacetone)palladium | 32005-36-0 | Pd | 18.50 - 22.00 | Solid | Pd(dba)2 | EMEA, APAC | Online available | |
5102254 | Osmium Tetroxide | 20816-12-0 | Os | 2 | Solution | OsO4 | EMEA, APAC, AMER | Online available | |
5102255 | Osmium Tetroxide | 20816-12-0 | Os | 4.00 | Solution | OsO4 | EMEA, APAC, AMER | Online available | |
5102256 | Ammonium Hexachloroosmate | 12125-08-5 | Os | 42.60 - 43.40 | Solid | (NH4)2OsCl6 | EMEA, APAC, AMER | Online available | |
5102321 | Osmium Tetroxide 2%, 2ml | 20816-12-0 | Os | 1.5 | Solution | OsO4 | EMEA, APAC, AMER | Online available | |
5102322 | Osmium Tetroxide 4%, 2ml | 20816-12-0 | Os | 3.00 | Solution | OsO4 | EMEA, APAC, AMER | Online available | |
5102323 | Osmium Tetroxide 2%, 5ml | 20816-12-0 | Os | 1.5 | Solution | OsO4 | EMEA, APAC, AMER | Online available | |
5102324 | Osmium Tetroxide 4%, 5ml | 20816-12-0 | Os | 3.00 | Solution | OsO4 | EMEA, APAC, AMER | Online available | |
5126789 | Rhodium Ethylene Dimer | 12081-16-2 | Rh | 52.00 - 53.00 | Solid | Rh2C8H16Cl2 | AMER | Request a quote | |
5126798 | Tris(dibenzylideneacetone)dipalladium | 52409-22-0 | Pd | 18.00 - 22.00 | Solid | Pd2(dba)3 | AMER | Request a quote | |
5126799 | Palladium Acetate | 3375-31-3 | Pd | 47.50 - 48.50 | Solid | Pd3(CH3COO)6 | AMER | Online available | |
5126831 | Potassium Tetrachloroplatinate | 10025-99-7 | Pt | 46.60 - 47.00 | Solid | K2PtCl4 | AMER | Online available | |
5126964 | Dichloro COD Platinum | 12080-32-9 | Pt | 51.00 - 53.00 | Solid | Pt(COD)Cl2 | AMER | Request a quote | |
5141870 | Tetrakis(triphenylphosphane)palladium | 14221-01-3 | Pd | 9.00 - 9.50 | Solid | Pd[(C6H5)3P]4 | AMER | Online available | |
5165047 | Bis[di-tert-butyl(p-dimethylaminophenyl)phosphino]palladium dichloride | 887919-35-9 | Pd | 14.00-16.00 | Solid | C32H56Cl2N2P2Pd | EMEA, APAC | Request a quote | |
5165589 | (1,3-Bis(diphenylphosphino) propane) palladium chloride | 59831-02-6 | Pd | 17.00-19.00 | Solid | C27H26P2PdCl2 | Request a quote | ||
81147163 | Di-µ-chloro-bis[(cycloocta-1,5-diene)iridium(I)] | 12112-67-3 | Ir | 56.00 - 58.00 | Solid | Ir2C16H24Cl2 | EMEA, APAC | Online available | |
81147177 | Di-µ-chloro-bis(cyclohexene)platinum(II) | 12176-53-3 | Pt | 54.50 - 56.50 | Solid | [{PtCl(C6H10)}2(µ-Cl)2] | EMEA, APAC | Online available | |
81147200 | Wilkinson's Catalyst | 14694-95-2 | Rh | 10.70 - 11.20 | Solid | Rh[(C6H5)3P]3Cl | EMEA, APAC | Online available | |
81147214 | Di-µ-chloro-bis[(cycloocta-1,5-diene)rhodium(I)] | 12092-47-6 | Rh | 40.00 - 42.00 | Solid | Rh2C16H24Cl2 | EMEA, APAC | Online available | |
81147221 | Cis-Diamminedichloroplatinum | 15663-27-1 | Pt | 64.90 - 65.20 | Solid | Pt(NH3)2Cl2 | EMEA, APAC | Online available | |
81147230 | Dichlorobis(triphenylphosphane)palladium | 13965-03-2 | Pd | 15.00 - 15.20 | Solid | PdC36H30Cl2P2 | EMEA, APAC | Online available | |
81147241 | Tetrakis(triphenylphosphane)palladium | 14221-01-3 | Pd | 9.00 - 9.70 | Solid | Pd[(C6H5)3P]4 | EMEA, APAC | Online available | |
81147247 | Tris(dibenzylideneacetone)dipalladium | 52409-22-0 | Pd | 18.50 - 22.00 | Solid | Pd2(dba)3 | EMEA, APAC | Online available | |
81147248 | Tris(dibenzylideneacetone)dipalladium Dibenzylideneacetone | 51364-51-3 | Pd | 18.50 - 22.00 | Solid | Pd2(dba)3 · DBA | EMEA, APAC | Online available | |
81147278 | Dichloro[1,1'-ferrocenylbis(diphenylphosphane)]palladium(II) dichloromethane | 95464-05-4 | Pd | 13.00-13.60 | Solid | C35H30Cl4FeP2Pd | EMEA, APAC | Online available | |
81147420 | Catalyst Rhodium Trichloride | 20765-98-4 | Rh | 37.00 - 42.00 | Solid | RhCl3 · 3H2O | EMEA, APAC | Online available | |
81147424 | Sodium Tetrachloropalladate | 13820-53-6 | Pd | 35.00 - 37.00 | Solid | Na2PdCl4 | EMEA, APAC | Online available | |
81147428 | Bis(dibenzylideneacetone)palladium | 32005-36-0 | Pd | 18.50 - 22.00 | Solid | Pd(dba)2 | EMEA, APAC | Online available | |
81147450 | Trinitratonitrosylruthenium | 34513-98-9 | Ru | 10.00 - 14.00 | Solution | Ru(NO)(NO3)3 | EMEA, APAC | Online available | |
81147473 | Rhodium 2-Ethylhexanoate | 20845-92-5 | Rh | 2.00 - 2.50 | Solution | Rh-2-EH | EMEA, APAC | Online available | |
81147487 | Rhodium Chloride | 13569-65-8 | Rh | 19.00 - 24.00 | Solution | RhCl3 | EMEA, APAC | Online available | |
81147501 | Tetraamminepalladium Chloride | 13815-17-3 | Pd | 9.00 - 11.00 | Solution | Pd(NH3)4Cl2 | EMEA, APAC | Online available | |
81152965 | Palladium Chloride (20%) | 16970-55-1 | Pd | 19.50 - 20.50 | Solution | H2PdCl4 | EMEA, APAC | Online available |
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Heraeus produces active pharmaceutical ingredients used for cancer medication. Furthermore, Heraeus also offers contract manufacturing of highly potent APIs.
Pharmaceutical Ingredients Portfolio
Complementary to our homogeneous catalyst portfolio, Heraeus also offers a broad range of heterogeneous catalysts (e.g. PGM on carbon) for the crop protection industry, pharma industry and other industries. This also includes catalysts for processes based on renewable feedstock (Green Chemistry).
Heraeus is a global leader in the production of osmium compounds – for example used in dihydroxylation reactions in the pharma and fine chemical industry..
Below we show some of the most common reaction types of pharmaceutical, agrochemical and fine chemical syntheses in which precious metal catalysts are applied.
Coupling reactions serve to link parts of an organic molecule by forming carbon-carbon bonds (C-C) or carbon nitrogen (C-N) bonds. Such reactions are used for pharmaceuticals, agro- and fine chemicals.
These coupling reactions are based on Pd(0) and Pd(II) precursors with added special ligands. Various coupling reactions (named after their inventors "Suzuki", "Matsuda", "Stille", etc.) are based on this palladium chemistry and play a crucial role in the efficient production of important products like biphenyls for pharma- and agrochemicals.
Heraeus has a broad portfolio of palladium phosphine catalysts as shown in our brochure. Depending on the coupling reaction of choice, one palladium phosphine catalyst may be preferred over the other. Moreover, Heraeus has developed a new phosphine ligand called SabPhos. As shown in our new brochure it is proven to build up C-N bonds in much milder conditions as other commonly used catalysts such as Xphos.